New process uses methane and steel slag to reduce cement emissions by 80%

By: | May 6th, 2025

This process uses solid waste from the steel industry as a catalyst to facilitate the reaction between calcium carbonate (CaCO₃) and methane (CH₄) under a CH₄ atmosphere, producing calcium oxide (CaO) and syngas (CO and H₂). The iron-based catalyst exhibits excellent catalytic performance and requires no separation, allowing it to be directly integrated into cement clinker production.(Image by Science China Press )

The Cement Industry’s Carbon Challenge

Cement manufacturing is responsible for nearly 8% of global CO₂ emissions, mainly due to the decomposition of limestone (CaCO₃) and the high energy input required. With the growing demand for sustainable construction, scientists are urgently seeking ways to reduce the carbon footprint of cement production.

Turning Waste into a Catalyst

In a recent study published in the National Science Review, researchers introduced an innovative process that uses steel solid waste (SSW) as a catalyst to lower CO₂ emissions during cement manufacturing. This waste, a byproduct of steel production, is rich in iron oxides and can facilitate the co-thermal reaction of calcium carbonate and methane (CH₄) at around 800°C.

A Dual Benefit Reaction

This reaction not only breaks down limestone with reduced carbon emissions but also partially oxidizes methane to produce hydrogen (H₂) and carbon monoxide (CO)—valuable industrial gases. Remarkably, the resulting solid residue, rich in iron and calcium, can be used directly in clinker formation, eliminating the need for catalyst separation.

Sustainable and Scalable

This process offers a significant step forward in green cement technology. By recycling industrial waste and lowering emissions, it supports a circular economy while aligning with global decarbonization goals. If scaled successfully, this method could revolutionize the cement industry and set a precedent for cross-sector waste valorization.

Nidhi Goyal

Nidhi is a gold medalist Post Graduate in Atmospheric and Oceanic Sciences.

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